Structure and magnetic properties of SmCo\u3csub\u3e7-x\u3c/sub\u3eTi\u3csub\u3ex\u3c/sub\u3e with TbCu\u3csub\u3e7\u3c/sub\u3e-type structure

摘要

The SmCo7-xTix, x = 0–0.56 bulk samples are prepared by arc melting. X-ray diffraction indicates that samples with 0.2\u3cx7-type structure phase and other minor phases appear for other values of x, which indicates that Ti helps stabilize the 1-7 phase. The lattice parameters ratio (c/a) increases with increasing Ti concentration. Room temperature saturation magnetization and Curie temperature decrease with increasing x. X-ray diffraction and magnetization measurements on aligned samples show that all samples studied have uniaxial anisotropy. The anisotropy field is found to increase with increasing x reaching a maximum of 175 kOe at x = 0.28 and then decreases for higher values of x. This anisotropy field is 20% higher than that of the same compound with Th2Zn17-type structure.